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Exhaust gas

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This diesel-powered truck emits an exhaust gas full of black particulate matter when starting up the engine.
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Exhaust gas or flue gas is emitted as a result of the combustion of fuels such as natural gas, gasoline (petrol), diesel fuel, fuel oil, biodiesel blends,[1] or coal. According to the type of engine, it is discharged into the atmosphere through an exhaust pipe, flue gas stack, or propelling nozzle. It often disperses downwind in a pattern called an exhaust plume.

It is a major component of motor vehicle emissions (and from stationary internal combustion engines), which can also include crankcase blow-by and evaporation of unused gasoline.

Motor vehicle emissions are a common source of air pollution and are a major ingredient in the creation of smog in some large cities. A 2013 study by the Massachusetts Institute of Technology (MIT) indicates that 53,000 early deaths occur per year in the United States alone because of vehicle emissions.[2] According to another study from the same university, traffic fumes alone cause the death of 5,000 people every year just in the United Kingdom.[3]

Composition

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The largest part of most combustion gas is nitrogen (N2), water vapor (H2O) (except with pure-carbon fuels), and carbon dioxide (CO2) (except for fuels without carbon); these are not toxic or noxious (although water vapor and carbon dioxide are greenhouse gases that contribute to climate change). A relatively small part of combustion gas is undesirable, noxious, or toxic substances, such as carbon monoxide (CO) from incomplete combustion, hydrocarbons (properly indicated as CxHy, but typically shown simply as "HC" on emissions-test slips) from unburnt fuel, nitrogen oxides (NOx) from excessive combustion temperatures, and particulate matter (mostly soot) from incomplete combustion.

Exhaust gas temperature

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Exhaust gas temperature (EGT) is important to the functioning of the catalytic converter of an internal combustion engine. It may be measured by an exhaust gas temperature gauge. EGT is also a measure of engine health in gas-turbine engines (see below).

Cold engines

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Steam from tailpipe of cold car

During the first two minutes after starting the engine of a car that has not been operated for several hours, the amount of emissions can be very high. This occurs for two main reasons:

  • Rich air-fuel ratio requirement in cold engines: When a cold engine is started, the fuel does not vaporize completely, creating higher emissions of hydrocarbons and carbon monoxide, which diminishes only as the engine reaches operating temperature. The duration of this start-up phase has been reduced by advances in materials and technology, including computer-controlled fuel injection, shorter intake lengths, and pre-heating of fuel and/or inducted air.
  • Inefficient catalytic converter under cold conditions: Catalytic converters are very inefficient until warmed up to their operating temperature. This time has been much reduced by moving the converter closer to the exhaust manifold and even more so placing a small yet quick-to-heat-up converter directly at the exhaust manifold. The small converter handles the start-up emissions, which allows enough time for the larger main converter to heat up. Further improvements can be realised in many ways,[4] including electric heating, thermal battery, chemical reaction preheating, flame heating and superinsulation.

Passenger car emissions summary

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U.S. Environmental Protection Agency estimates of average passenger car emissions in the United States for April 2000[5]
Component Emission Rate Annual pollution emitted
Hydrocarbons 2.80 grams/mile (1.75 g/km) 77.1 pounds (35.0 kg)
Carbon monoxide 20.9 grams/mile (13.06 g/km) 575 pounds (261 kg)
NOx 1.39 grams/mile (0.87 g/km) 38.2 pounds (17.3 kg)
Carbon dioxide - greenhouse gas 415 grams/mile (258 g/km) 11,450 pounds (5,190 kg)

Comparable with the European emission standards EURO III as it was applied in October 2000

In 2000, the United States Environmental Protection Agency began to implement more stringent emissions standards for light duty vehicles. The requirements were phased in beginning with 2004 vehicles and all new cars and light trucks were required to meet the updated standards by the end of 2007.

United States Light-Duty Vehicle, Light-Duty Truck, and Medium-Duty Passenger Vehicle—Tier 2 Exhaust Emission Standards (for Bin 5)[6]
Component Emission Rate Annual pollution emitted
NMOG (Volatile organic compounds) 0.075  grams/mile (0.046 g/km) 2.1 pounds (0.95 kg)
Carbon Monoxide 3.4 grams/mile (2.1 g/km) 94 pounds (43 kg)
NOX 0.05 grams/mile (0.0305 g/km) 1.4 pounds (0.64 kg)
Formaldehyde 0.015 grams/mile (0.0092 g/km) 0.41 pounds (0.19 kg)

Types

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Internal-combustion engines

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Automobile exhaust

Spark-ignition and Diesel engines

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See also: Automobile emissions control

In spark-ignition engines the gases resulting from combustion of the fuel and air mix are called exhaust gases. The composition varies from petrol to diesel engines, but is around these levels:

Combustion-engine exhaust gases[7]
All figures are approximate
Compound % of total
Petrol Diesel
Nitrogen 71 67
Carbon dioxide 14 12
Water vapor 13 11
Oxygen 10
Trace elements[citation needed] < 0.6 ~ 0.3
Nitrogen oxides < 0.25 < 0.15
Carbon monoxide 1 - 2 < 0.045
Particulate matter < 0.045
Hydrocarbons < 0.25 < 0.03
Sulfur dioxide Possible
traces 		< 0.03

The 10% oxygen for "diesel" is likely if the engine was idling, e.g. in a test rig. It is much less if the engine is running under load, although diesel engines always operate with an excess of air over fuel. [citation needed] The CO content for petrol engines varies from ≈15 ppm for well tuned engine with fuel injection and a catalytic converter up to 100,000 ppm (10%) for a richly tuned carburetor engine, such as typically found on small generators and garden equipment.[8]

Nitromethane additive
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Exhaust gas from an internal combustion engine whose fuel includes nitromethane will contain nitric acid vapour, which is corrosive, and when inhaled causes a muscular reaction making it impossible to breathe. People who are likely to be exposed to it should wear a gas mask.[9]

Diesel engines

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See also: Soot
These paragraphs are an excerpt from Diesel exhaust.[edit]

Diesel exhaust is the exhaust gas produced by a diesel engine, plus any contained particulates. Its composition may vary with the fuel type or rate of consumption, or speed of engine operation (e.g., idling or at speed or under load), and whether the engine is in an on-road vehicle, farm vehicle, locomotive, marine vessel, or stationary generator or other application.[10]

Diesel exhaust is a Group 1 carcinogen, which causes lung cancer and has a positive association with bladder cancer.[11][12][13][14][15] It contains several substances that are also listed individually as human carcinogens by the IARC.[16]

Methods exist to reduce nitrogen oxides (NOx) and particulate matter (PM) in the exhaust. So, while diesel fuel contains slightly more carbon (2.68 kg CO2/litre) than petrol (2.31 kg CO2/litre), overall CO2 emissions of a diesel car tend to be lower due to higher efficiency. In use, on average, this equates to around 200 g CO2/km for petrol and 120 g CO2/km for diesel.

Gas-turbine engines

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In aircraft gas turbine engines, "exhaust gas temperature" (EGT) is a primary measure of engine health. Typically the EGT is compared with a primary engine power indication called "engine pressure ratio" (EPR). For example: at full power EPR there will be a maximum permitted EGT limit. Once an engine reaches a stage in its life where it reaches this EGT limit, the engine will require specific maintenance in order to rectify the problem. The amount the EGT is below the EGT limit is called EGT margin. The EGT margin of an engine will be greatest when the engine is new, or has been overhauled. For most airlines, this information is also monitored remotely by the airline maintenance department by means of ACARS.

Jet engines and rocket engines

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What looks like exhaust from jet engines is actually contrails.

In jet engines and rocket engines, exhaust from propelling nozzles which in some applications shows shock diamonds.[citation needed]

Other types

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From burning coal

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Flue gas is that emitted from ovens, furnaces and boilers.

Steam engines

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In steam engine terminology the exhaust is steam that is now so low in pressure that it can no longer do useful work.

Main motor vehicle emissions

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NOx

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Smog in New York City as viewed from the World Trade Center in 1988

Mono-nitrogen oxides NO and NO2 (NOx) (whether produced this way or naturally by lightning) react with ammonia, moisture, and other compounds to form nitric acid vapor and related particles. Small particles can penetrate deeply into sensitive lung tissue and damage it, causing premature death in extreme cases. Inhalation of NO species increases the risk of lung cancer[17] and colorectal cancer.[18] and inhalation of such particles may cause or worsen respiratory diseases such as emphysema and bronchitis and heart disease.[19][20][21]

In a 2005 U.S. EPA study the largest emissions of NOx came from on road motor vehicles, with the second largest contributor being non-road equipment which is mostly gasoline and diesel stations.[21]

The resulting nitric acid may be washed into soil, where it becomes nitrate, which is useful to growing plants.

Volatile organic compounds

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Non-road equipment is mostly gasoline and diesel stations.[22]

When oxides of nitrogen (NOx) and volatile organic compounds (VOCs) react in the presence of sunlight, ground level ozone is formed, a primary ingredient in smog. A 2005 U.S. EPA report gives road vehicles as the second largest source of VOCs in the U.S. at 26% and 19% are from non road equipment which is mostly gasoline and diesel stations.[22] 27% of VOC emissions are from solvents which are used in the manufacturer of paints and paint thinners and other uses.[23]

Ozone

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Ozone is beneficial in the upper atmosphere,[24] but at ground level ozone irritates the respiratory system, causing coughing, choking, and reduced lung capacity.[25] It also has many negative effects throughout the ecosystem.[26]

Carbon monoxide (CO)

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MOPITT satellite computer image of carbon monoxide March 2010

Carbon monoxide poisoning is the most common type of fatal air poisoning in many countries.[27] Carbon monoxide is colorless, odorless and tasteless, but highly toxic. It combines with hemoglobin to produce carboxyhemoglobin, which blocks the transport of oxygen. At concentrations above 1000ppm it is considered immediately dangerous and is the most immediate health hazard from running engines in a poorly ventilated space. In 2011, 52% of carbon monoxide emissions were created by mobile vehicles in the U.S.[28]

Hazardous air pollutants (toxics)

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Chronic (long-term) exposure to benzene (C6H6) damages bone marrow. It can also cause excessive bleeding and depress the immune system, increasing the chance of infection. Benzene causes leukemia and is associated with other blood cancers and pre-cancers of the blood.[29][30]

Particulate matter (PM10 and PM2.5)

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The health effects of inhaling airborne particulate matter have been widely studied in humans and animals and include asthma, lung cancer, cardiovascular issues, premature death.[31][32][33] Because of the size of the particles, they can penetrate the deepest part of the lungs.[34] A 2011 UK study estimates 90 deaths per year due to passenger vehicle PM.[35] In a 2006 publication, the U.S. Federal Highway Administration (FHWA) state that in 2002 about 1 per-cent of all PM10 and 2 per-cent of all PM2.5 emissions came from the exhaust of on-road motor vehicles (mostly from diesel engines).[36] In Chinese, European, and Indian markets, both diesel and gasoline vehicles are required to have a tailpipe filter installed, while the United States has mandated it for diesel only. In 2022, British testing specialist Emissions Analytics estimated that the 300 million or so gasoline vehicles in the US over the subsequent decade would emit around 1.6 septillion harmful particles.[37]

Carbon dioxide (CO2)

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Carbon dioxide is a greenhouse gas. Motor vehicle CO2 emissions are part of the anthropogenic contribution to the growth of CO2 concentrations in the atmosphere which according to the vast majority of the scientific community is causing climate change.[38] Motor vehicles are calculated to generate about 20% of the European Union's man-made CO2 emissions, with passenger cars contributing about 12%.[39] European emission standards limit the CO2 emissions of new passenger cars and light vehicles. The European Union average new car CO2 emissions figure dropped by 5.4% in the year to the first quarter of 2010, down to 145.6 g/km.[40]

Water vapour

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Vehicle exhaust contains much water vapour.

Water recovery

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There has been research into ways that troops in deserts can recover drinkable water from their vehicles' exhaust gases.[41]

Pollution reduction

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See also: Air suction valve and Vehicle-specific power

Emission standards focus on reducing pollutants contained in the exhaust gases from vehicles as well as from industrial flue gas stacks and other air pollution exhaust sources in various large-scale industrial facilities such as petroleum refineries, natural gas processing plants, petrochemical plants and chemical production plants.[42][43] However, these are often referred to as flue gases. Catalytic converters in cars intend to break down the pollution of exhaust gases using a catalyst. Scrubbers in ships intend to remove the sulfur dioxide (SO2) of marine exhaust gases. The regulations on marine sulfur dioxide emissions are tightening, however only a small number of special areas worldwide have been designated for low sulfur diesel fuel use only.

One of the advantages claimed for advanced steam technology engines is that they produce smaller quantities of toxic pollutants (e.g. oxides of nitrogen) than petrol and diesel engines of the same power.[citation needed] They produce larger quantities of carbon dioxide but less carbon monoxide due to more efficient combustion.

Health studies

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Researchers from the University of California, Los Angeles School of Public Health say preliminary results of their statistical study of children listed in the California Cancer Registry born between 1998 and 2007 found that traffic pollution may be associated with a 5% to 15% increase in the likelihood of some cancers.[44] A World Health Organization study found that diesel fumes cause an increase in lung cancer.[45]

Localised effects

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The California Air Resources Board found in studies that 50% or more of the air pollution (smog) in Southern California is due to car emissions.[citation needed] Concentrations of pollutants emitted from combustion engines may be particularly high around signalized intersections because of idling and accelerations. Computer models often miss this kind of detail.[46]

See also

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References

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  1. ^ Omidvarborna; et al. (2014). "Characterization of particulate matter emitted from transit buses fueled with B20 in idle modes". Journal of Environmental Chemical Engineering. 2 (4): 2335–2342. doi:10.1016/j.jece.2014.09.020.
  2. ^ Caiazzo, Fabio; Ashok, Akshay; Waitz, Ian A.; Yim, Steve H.L.; Barrett, Steven R.H. (November 2013). "Air pollution and early deaths in the United States. Part I: Quantifying the impact of major sectors in 2005". Atmospheric Environment. 79: 198–208. Bibcode:2013AtmEn..79..198C. doi:10.1016/j.atmosenv.2013.05.081.
  3. ^ Roland Pease. "Traffic pollution kills 5,000 a year in UK, says study". BBC News.
  4. ^ Pulkrabek W.W. (2004) Engineering Fundamentals of the Internal Combustion Engine. Pearson Prentice Hall, new Jersey
  5. ^ "Average Annual Emissions and Fuel Consumption for Passenger Cars and Light Trucks" (PDF). Transportation and Air Quality. United States Environmental Protection Agency. 19 August 2015.
  6. ^ "Light-Duty Vehicle, Light-Duty Truck, and Medium-Duty Passenger Vehicle -- Tier 2 Exhaust Emission Standards". Emission Standards Reference Guide. United States Environmental Protection Agency. 14 November 2012.
  7. ^ Self-Study Programme 230: Motor Vehicle Exhaust Emissions (PDF). AUDI. April 2000. Retrieved 23 March 2012.
  8. ^ "Carbon Monoxide Poisoning: Operating Fossil Fuel Engines Inside Buildings (AEN-206)". Department of Agricultural and Biosystems Engineering. Retrieved 18 June 2023.
  9. ^ "Race Fuel - Nitromethane". www.turbofast.com.au. Archived from the original on 13 March 2018. Retrieved 23 January 2008.
  10. ^ Lippmann, Morton, ed. (2009). Environmental Toxicants (PDF). pp. 553, 555, 556, 562. doi:10.1002/9780470442890. ISBN 9780470442890. composition can vary markedly with fuel composition, engine type, operating conditions ... combustion of petroleum fuel produces primarily carbon dioxide, water, and nitrogen ... The health risks lie in the small, invisible or poorly visible particles ... carbon (EC) core of diesel soot ... serves as a nucleus for condensation of organic compounds from unburned or incompletely burned fuel ... it still appears that nitrated PAHs are the most predominant bacterial mutagens
  11. ^ "IARC: DIESEL ENGINE EXHAUST CARCINOGENIC" (Press release). International Agency for Research on Cancer (IARC). 12 June 2012. Retrieved 14 August 2016. The scientific evidence was reviewed thoroughly by the Working Group and overall it was concluded that there was sufficient evidence in humans for the carcinogenicity of diesel exhaust. The Working Group found that diesel exhaust is a cause of lung cancer (sufficient evidence) and also noted a positive association (limited evidence) with an increased risk of bladder cancer
  12. ^ "Report on Carcinogens: Diesel Exhaust Particulates" (PDF). National Toxicology Program, Department of Health and Human Services. 2 October 2014. Exposure to diesel exhaust particulates is reasonably anticipated to be a human carcinogen, based on limited evidence of carcinogenicity from studies in humans and supporting evidence from studies in experimental animals and mechanistic studies.
  13. ^ "Diesel engine exhaust; CASRN N.A." (PDF). U.S. Environmental Protection Agency. 28 February 2003. Using U.S. EPA's revised draft 1999 Guidelines for Carcinogen Risk Assessment (U.S. EPA, 1999), diesel exhaust (DE) is likely to be carcinogenic to humans by inhalation from environmental exposures.
  14. ^ Silverman, Debra T.; Samanic, Claudine M.; Lubin, Jay H.; Blair, Aaron E.; Stewart, Patricia A.; Vermeulen, Roel; Coble, Joseph B.; Rothman, Nathaniel; Schleiff, Patricia L. (6 June 2012). "The Diesel Exhaust in Miners study: a nested case-control study of lung cancer and diesel exhaust". Journal of the National Cancer Institute. 104 (11): 855–868. doi:10.1093/jnci/djs034. ISSN 1460-2105. PMC 3369553. PMID 22393209.
  15. ^ Attfield, Michael D.; Schleiff, Patricia L.; Lubin, Jay H.; Blair, Aaron; Stewart, Patricia A.; Vermeulen, Roel; Coble, Joseph B.; Silverman, Debra T. (6 June 2012). "The Diesel Exhaust in Miners study: a cohort mortality study with emphasis on lung cancer". Journal of the National Cancer Institute. 104 (11): 869–883. doi:10.1093/jnci/djs035. ISSN 1460-2105. PMC 3373218. PMID 22393207.
  16. ^ IARC. "Diesel Engine Exhaust Carcinogenic" (Press release). International Agency for Research on Cancer (IARC). Retrieved 12 June 2012. After a week-long meeting of international experts, the International Agency for Research on Cancer (IARC), which is part of the World Health Organization (WHO), today classified diesel exhaust as probably carcinogenic to humans (Group 1), based on enough evidence that exposure is associated with an increased risk of lung cancer.
  17. ^ Hamra, GB; Laden, F; Cohen, AJ; Raaschou-Nielsen, O; Brauer, M; Loomis, D (November 2015). "Lung Cancer and Exposure to Nitrogen Dioxide and Traffic: A Systematic Review and Meta-Analysis". Environmental Health Perspectives. 123 (11): 1107–12. doi:10.1289/ehp.1408882. PMC 4629738. PMID 25870974.
  18. ^ Turner, MC; Krewski, D; Diver, WR; Pope CA, 3rd; Burnett, RT; Jerrett, M; Marshall, JD; Gapstur, SM (21 August 2017). "Ambient Air Pollution and Cancer Mortality in the Cancer Prevention Study II". Environmental Health Perspectives. 125 (8): 087013. doi:10.1289/EHP1249. PMC 5783657. PMID 28886601.{{cite journal}}: CS1 maint: numeric names: authors list (link) Open access icon
  19. ^ "Health". Nitrogen Dioxide. United States Environmental Protection Agency. 14 February 2013.
  20. ^ "The Regional Transport of Ozone: New EPA Rulemaking on Nitrogen Oxide Emissions (EPA-456/F-98-006)" (PDF). United States Environmental Protection Agency. September 1998.
  21. ^ a b "State and County Emission Summaries: Nitrogen Oxides". Air emission sources. United States Environmental Protection Agency. 25 October 2013.
  22. ^ a b "State and County Emission Summaries: Volatile Organic Compounds". Air emission sources. United States Environmental Protection Agency. 25 October 2013.
  23. ^ "Volatile Organic Compounds (VOCs)". Toxic Substances Hydrology Program. United States Geological Survey (USGS). 12 April 2013. Archived from the original on 5 September 2015. Retrieved 2 June 2014.
  24. ^ EPA, OAR, OAP, SPD, US. "Ozone Layer Protection - US EPA". US EPA.{{cite web}}: CS1 maint: multiple names: authors list (link)
  25. ^ "Air Quality Planning and Standards".
  26. ^ "Ecosystem Effects | Ground-level Ozone | US EPA". www.epa.gov. Archived from the original on 18 May 2012.
  27. ^ Omaye ST. (2002). "Metabolic modulation of carbon monoxide toxicity". Toxicology. 180 (2): 139–150. doi:10.1016/S0300-483X(02)00387-6. PMID 12324190.
  28. ^ "State and County Emission Summaries: Carbon Monoxide". Air Emission Sources. United States Environmental Protection Agency. 25 October 2013.
  29. ^ "Exhaust emissions: What comes out of your car's exhaust?". Automobile Association Developments Limited. 23 February 2012.
  30. ^ "Air Toxics from Motor Vehicles" (PDF). Transportation and Air Quality. United States Environmental Protection Agency.
  31. ^ Kurt, OK; Zhang, J; Pinkerton, KE (March 2016). "Pulmonary health effects of air pollution". Current Opinion in Pulmonary Medicine. 22 (2): 138–43. doi:10.1097/MCP.0000000000000248. PMC 4776742. PMID 26761628.
  32. ^ Bourdrel, T; Bind, MA; Béjot, Y; Morel, O; Argacha, JF (November 2017). "Cardiovascular effects of air pollution". Archives of Cardiovascular Diseases. 110 (11): 634–642. doi:10.1016/j.acvd.2017.05.003. PMC 5963518. PMID 28735838.
  33. ^ Babadjouni, RM; Hodis, DM; Radwanski, R; Durazo, R; Patel, A; Liu, Q; Mack, WJ (September 2017). "Clinical effects of air pollution on the central nervous system; a review". Journal of Clinical Neuroscience. 43: 16–24. doi:10.1016/j.jocn.2017.04.028. PMC 5544553. PMID 28528896.
  34. ^ Region 4: Laboratory and Field Operations — PM 2.5 (2008).PM 2.5 Objectives and History. U.S. Environmental Protection Agency.
  35. ^ Mazzi, Eric A.; Dowlatabadi, Hadi (2007). "Air Quality Impacts of Climate Mitigation: UK Policy and Passenger Vehicle Choice". Environmental Science & Technology. 41 (2): 387–92. Bibcode:2007EnST...41..387M. doi:10.1021/es060517w. PMID 17310696.
  36. ^ "Transportation Air Quality: Selected Facts and Figures". U.S. Department of Transportation Federal Highway Commission. 2006. Archived from the original on 16 June 2006. Retrieved 14 April 2010.
  37. ^ Lewis, Barbara; Carey, Nick (27 April 2022). "Lacking filters, U.S. cars set to emit a septillion more particles - research". Reuters.
  38. ^ IPCC, 2013: Summary for Policymakers. In: Climate Change 2013: The Physical Science Basis. Contribution of Working Group I to the Fifth Assessment Report of the Intergovernmental Panel on Climate Change [Stocker, T.F., D. Qin, G.-K. Plattner, M. Tignor, S.K. Allen, J. Boschung, A. Nauels, Y. Xia, V. Bex and P.M. Midgley (eds.). Cambridge University Press, Cambridge, United Kingdom and New York, NY, USA.
  39. ^ "Commission plans legislative framework to ensure the EU meets its target for cutting CO2 emissions from cars". European Commission. 7 February 2007.
  40. ^ "EU Average New Car CO2 Emissions Down 5.4 Percent in Q1". autoevolution. SoftNews NET. 19 April 2010.
  41. ^ "recovering water from diesel exhaust - Google Search". www.google.co.uk.
  42. ^ "EPA Plain English Guide to the Clean Air Act". Retrieved 18 June 2023.
  43. ^ US EPA Publication AP 42, Fifth Edition, Compilation of Air Pollutant Emission Factors
  44. ^ Reinberg, Steven (9 April 2013). "Smog Exposure During Pregnancy Might Raise Child's Cancer Risk: Study". USNews.
  45. ^ "IARC Diesel engine exhaust carcinogenic". iarc.fr. Retrieved 18 June 2023.
  46. ^ Int Panis L; et al. (2006). "Modelling instantaneous traffic emission and the influence of traffic speed limits". Science of the Total Environment. 371 (1–3): 270–285. Bibcode:2006ScTEn.371..270I. doi:10.1016/j.scitotenv.2006.08.017. PMID 17049967.
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